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Noble-metal-free cobalt hydroxide nanosheets for efficient electrocatalytic oxidation

Jie Lan, Daizong Qi, Jie Song, Peng Liu, Yi Liu, Yun-Xiang Pan

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 948-955 doi: 10.1007/s11705-020-1920-2

Abstract: Cobalt hydroxide has been emerging as a promising catalyst for the electrocatalytic oxidation reactionsHerein, we prepared cobalt hydroxide nanoparticles (CoHP) and cobalt hydroxide nanosheets (CoHS) on nickel

Keywords： electrocatalytic oxidation     cobalt hydroxide     nanosheet     water     glucose    

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Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layereddouble hydroxide for high-performance nonenzymatic glucose sensors

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1593-1607 doi: 10.1007/s11705-023-2348-2

Abstract: utilized as a substrate to integrate highly conductive polypyrrole and active nanoflower-like nickel-cobaltlayered double hydroxide through in situ chemical polymerization and electrodeposition.

Keywords： cellulose nanofibril     aerogel     nickel-cobalt layered double hydroxide     polypyrrole     nonenzymatic glucose    

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Synthesis and electrocatalytic property of cubic and spherical nanoparticles of cobalt platinum alloys

Xiaowei TENG, Hong YANG,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 1,   Pages 45-51 doi: 10.1007/s11705-009-0308-0

Abstract: Both cubic and spherical CoPt nanoparticles were made using cobalt carbonyl and platinum 2,4-pentanedionateEffects of heterogeneous species on shape of the CoPt nanoparticles were examined by replacing cobaltthat the formation of different shapes of CoPt particles could be attributed to the affinity between cobalt

Keywords： spherical     2     4-pentanedionate     adamantanecarboxylic     acetylacetonate     electrocatalytic    

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Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1550-1560 doi: 10.1007/s11705-021-2104-4

Abstract: In this work, cobalt nanoparticle decorated N-doped carbons (Co@NC) are synthesized by the pyrolysisof a cobalt covalent organic framework under an inert atmosphere.compared to N-doped carbon without the addition of Co nanoparticles, indicating the important role of cobalt

Keywords： cobalt embedment     N-doped carbons     covalent organic framework     oxygen reduction     Zn-air battery    

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Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1440-1449 doi: 10.1007/s11705-023-2333-9

Abstract: was successfully prepared using a one-step hydrothermal method under the in-situ doping of the cobaltThe effects of in-situ doping of the cobalt element on the micromorphology and electrochemicalAfter in-situ doping of the cobalt element, NiS with a needle-like structure was converted intoThis result indicated that the in-situ doping of the cobalt element promoted the electrochemical

Keywords： MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

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A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 6,   Pages 945-951 doi: 10.1007/s11783-013-0615-z

Abstract: A potentiometric cobalt-based screen-printing sensor was fabricated by electroplating cobalt on the surfaceThe cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10

Keywords： phosphate     cobalt     screen-printing technology     electroplate     wastewater    

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Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4,   Pages 416-421 doi: 10.1007/s11705-011-1125-9

Abstract: Magnesium hydroxide with high purity and uniform particle size distribution was synthesized by the directThe particle size distribution, crystal phase, morphology, and surface area of magnesium hydroxide weresynthesis conditions on the particle size distribution and water content (filtration cake) of magnesium hydroxidedistribution of the product, and sodium chloride improved the crystallization behavior of magnesium hydroxideand mild synthesis method was promising to be scaled up for the industrial production of magnesium hydroxide

Keywords： magnesium hydroxide     direct precipitation method     industrial crystallization     particle size distribution    

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Room temperature oxidation of acetone by ozone over alumina-supported manganese and cobalt mixed oxides

Mehraneh Ghavami, Mostafa Aghbolaghy, Jafar Soltan, Ning Chen

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 937-947 doi: 10.1007/s11705-019-1900-6

Abstract: In this study, a series of alumina supported single and mixed manganese and cobalt oxides catalysts wereThe manganese and cobalt single and mixed oxides catalysts of the formula Mn10%-CoX and Co10%-MnX (where

Keywords： ozone     VOC     manganese oxides     cobalt oxides     alumina support    

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Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: Role of support

Hasan Oliaei Torshizi, Ali Nakhaei Pour, Ali Mohammadi, Yahya Zamani, Seyed Mehdi Kamali Shahri

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 2,   Pages 299-309 doi: 10.1007/s11705-020-1925-x

Abstract: In this paper, a series of cobalt catalysts supported on reduced graphene oxide (rGO) nanosheets withThe results showed that with increasing the cobalt loading on the rGO support, the carbon defects areincreased and as a consequence, the reduction of cobalt is decreased.The FTS activity results showed that the cobalt-time yield and turnover frequency passed from a maximumthat the methane selectivity decreases, whereas the C selectivity raises with the increasing of the cobalt

Keywords： cobalt catalyst     cobalt particle size     Fischer-Tropsch synthesis     reduced graphene oxide     supported catalyst    

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Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 9,   Pages 1367-1376 doi: 10.1007/s11705-022-2153-3

Abstract: Herein, a novel metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrid was developedby a carbothermal reduction of cobalt/nickel phosphonate hybrids with different Co/Ni molar ratios.

Keywords： metal phosphonate     cobalt/nickel phosphide     N-doped carbon     oxygen electrochemistry     Zn−air battery    

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Experimental studies on extraction of cobalt ions from dilute aqueous solutions by using complexation-ultrafiltration

Jianxian ZENG, Junfeng LIU, Niandong HUANG,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 3,   Pages 360-366 doi: 10.1007/s11705-009-0269-3

Abstract: The extraction of cobalt ions from dilute aqueous solutions was investigated by ultrafiltration withindicated that loading ratio, pH value and low-molecular competitive complexing agent affect significantly cobaltThe decomplexation ratio of cobalt-PAASS complex reaches as high as 90.1%.Cobalt ions can be extracted satisfactorily from the retentate, and a purified PAASS is obtained.
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Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting

Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 537-554 doi: 10.1007/s11705-018-1719-6

Abstract: Recently, layered double hydroxide (LDH)-based materials have gained increasing attentions as promising

Keywords： layered double hydroxides (LDHs)     core-shell nanoarrays     oxygen evolution reaction (OER)     hydrogen evolution reaction (HER)     photoelectrochemical water splitting (PEC)    

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Synthesis of cobalt vanadium nanomaterials for efficient electrocatalysis of oxygen evolution

Meifeng Hao, Mingshu Xiao, Lihong Qian, Yuqing Miao

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 409-416 doi: 10.1007/s11705-017-1689-0

Abstract:

A low-cost and high-activity catalyst for oxygen evolution reaction (OER) is the key to the water splitting technology for hydrogen generation. Here we report the use of three solvents, DMF, ethanol and glycol, in the solvothermal synthesis of three nano-catalysts, Co3(VO4)2-I, Co3(VO4)2-II, and Co3(VO4)2-III, respectively. Transmission electron microscope shows Co3(VO4)2-I, II, and III exist as ultrafine nanosheets, ultrathin nanofilms, and ultrafine nanosheet-comprised microspheres, respectively. These Co3(VO4)2 catalysts exhibit OER electrocatalysis, among which the Co3(VO4)2-II shows the lowest onset overpotential of 310 mV and only requires a small overpotential of 330 mV to drive current density of 10 mA/cm2. Due to their high surface free energy, the ultrathin nanofilms of Co3(VO4)2-II exhibits a good immobilization effect with the high electrocatalytic activity for OER.

Keywords： Co3(VO4)2     oxygen evolution reaction     electrocatalyst     water splitting    

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Defective Nickle–Iron Layered Double Hydroxide for Enhanced Photocatalytic NO Oxidation with Significant

Xiaoyu Li,Xiaoshu Lv,Jian Pan,Peng Chen,Huihui Peng,Yan Jiang,Haifeng Gong,Guangming Jiang,Li'an Hou,

Engineering doi: 10.1016/j.eng.2023.06.017

Abstract: candidate photocatalysts owing to their unique layered and tunable chemical structures, and the abundant hydroxide

Keywords： Vacancies     Layered double hydroxide     NO     +     Photocatalysis     NO removal    

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Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1487-1499 doi: 10.1007/s11705-021-2085-3

Abstract: Developing cost-effective electrocatalysts for oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is vital in energy conversion and storage applications. Herein, we report a simple method for the synthesis of graphene-reinforced CoS/C nanocomposites and the evaluation of their electrocatalytic performance for typical electrocatalytic reactions. Nanocomposites of CoS embedded in N, S co-doped porous carbon and graphene (CoS@C/Graphene) were generated via simultaneous sulfurization and carbonization of one-pot synthesized graphite oxide-ZIF-67 precursors. The obtained CoS@C/Graphene nanocomposites were characterized by X-ray diffraction, Raman spectroscopy, thermogravimetric analysis-mass spectroscopy, scanning electronic microscopy, transmission electronic microscopy, X-ray photoelectron spectroscopy and gas sorption. It is found that CoS nanoparticles homogenously dispersed in the in situ formed N, S co-doped porous carbon/graphene matrix. The CoS@C/10Graphene composite not only shows excellent electrocatalytic activity toward ORR with high onset potential of 0.89 V, four-electron pathway and superior durability of maintaining 98% of current after continuously running for around 5 h, but also exhibits good performance for OER and HER, due to the improved electrical conductivity, increased catalytic active sites and connectivity between the electrocatalytic active CoS and the carbon matrix. This work offers a new approach for the development of novel multifunctional nanocomposites for the next generation of energy conversion and storage applications.

Keywords： MOF derivative     graphene     electrocatalyst     oxygen reduction reaction     oxygen evolution reaction     hydrogen evolution reaction    

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Title Author Date Type Operation

Noble-metal-free cobalt hydroxide nanosheets for efficient electrocatalytic oxidation

Jie Lan, Daizong Qi, Jie Song, Peng Liu, Yi Liu, Yun-Xiang Pan

Journal Article

Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layereddouble hydroxide for high-performance nonenzymatic glucose sensors

Journal Article

Synthesis and electrocatalytic property of cubic and spherical nanoparticles of cobalt platinum alloys

Xiaowei TENG, Hong YANG,

Journal Article

Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

Journal Article

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

Journal Article

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

Journal Article

Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

Journal Article

Room temperature oxidation of acetone by ozone over alumina-supported manganese and cobalt mixed oxides

Mehraneh Ghavami, Mostafa Aghbolaghy, Jafar Soltan, Ning Chen

Journal Article

Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: Role of support

Hasan Oliaei Torshizi, Ali Nakhaei Pour, Ali Mohammadi, Yahya Zamani, Seyed Mehdi Kamali Shahri

Journal Article

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen

Journal Article

Experimental studies on extraction of cobalt ions from dilute aqueous solutions by using complexation-ultrafiltration

Jianxian ZENG, Junfeng LIU, Niandong HUANG,

Journal Article

Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting

Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei

Journal Article

Synthesis of cobalt vanadium nanomaterials for efficient electrocatalysis of oxygen evolution

Meifeng Hao, Mingshu Xiao, Lihong Qian, Yuqing Miao

Journal Article

Defective Nickle–Iron Layered Double Hydroxide for Enhanced Photocatalytic NO Oxidation with Significant

Xiaoyu Li,Xiaoshu Lv,Jian Pan,Peng Chen,Huihui Peng,Yan Jiang,Haifeng Gong,Guangming Jiang,Li'an Hou,

Journal Article

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Journal Article